4-Chloro-N-(2,4-dimethylphenyl)-2-methylbenzenesulfonamide
نویسندگان
چکیده
In the title compound, C(15)H(16)ClNO(2)S, the C-SO(2)-NH-C torsion angle is 67.45 (17)°. The two aromatic rings are tilted relative to each other by 44.5 (1)°. The crystal structure features inversion-related dimers linked by pairs of N-H⋯O hydrogen bonds..
منابع مشابه
4-Chloro-N-(2,6-dimethylphenyl)-2-methylbenzenesulfonamide
In the title compound, C(15)H(16)ClNO(2)S, the C-SO(2)-NH-C torsion angle is -61.15 (16)°. The sulfonyl and aniline benzene rings are tilted relative to each other by 38.8 (1)°. The crystal structure features inversion-related dimers linked by pairs of N-H⋯O hydrogen bonds.
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In the title compound, C(15)H(16)ClNO(2)S, the conformation of the N-C bond in the C-SO(2)-NH-C segment is gauche with respect to the S=O bonds. Further, the N-H bond in the C-SO(2)-NH-C segment is syn with respect to the meta-methyl group in the aniline benzene ring and the ortho-methyl group in the sulfonyl benzene ring. The C-SO(2)-NH-C torsion angle is -49.72 (18)°. The sulfonyl and aniline...
متن کامل4-Chloro-N-(2,5-dimethylphenyl)-2-methylbenzenesulfonamide
The asymmetric unit of the title compound, C(15)H(16)ClNO(2)S, contains three independent moleules. The conformation of the N-H bonds are anti to the ortho-methyl groups of the sulfonyl benzene rings in all the mol-ecules. The sulfonyl and the aniline benzene rings are tilted relative to each other by 43.0 (2), 37.0 (2) and by 46.0 (1)° in the three mol-ecules. In the crystal, inter-molecular N...
متن کاملN-(3,5-Dimethylphenyl)-4-methylbenzenesulfonamide
In the title compound, C(15)H(17)NO(2)S, the dihedral angle between the two aromatic rings is 53.9 (1)°. The crystal structure features inversion-related dimers linked by N-H⋯O hydrogen bonds.
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The conformation of the N-H bond in the structure of the title compound, C(10)H(12)ClNO, is syn to the ortho methyl group, similar to that observed with respect to the meta methyl group in 2-chloro-N-(3-methyl-phen-yl)acetamide and the ortho-chloro group in 2-chloro-N-(2-chloro-phen-yl)acetamide. The geometric parameters are similar to those of other acetanilides. The mol-ecules are linked into...
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